By P. Ruiz, B. Delmon
This quantity comprises invited papers and communications offered on the 3rd ecu Workshop assembly on Selective Oxidation via Heterogeneous Catalysis. the aim of the assembly used to be to offer fresh effects and to debate new features of partial oxidation through heterogeneous catalysis. the subsequent subject matters have been mentioned: Novel strategies for acquiring new effective chemical substances by means of catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in instruction equipment of oxidation catalysts; new phenomena in partial oxidation and new facets of floor chemistry in oxide catalysts; new purposes of physicochemical equipment for characterization of oxide catalysts; oxidation with different brokers than oxygen and catalytic oxidation of carbohydrates.
This booklet will supply a priceless set of knowledge on reactions of selective oxidation on the way to be tremendous invaluable to catalyst and comparable practitioners, even if fundamentalists or hugely utilized, and to method engineers who desire to overview present findings during this box. The wide-range method of reactions of selective oxidation will disseminate wisdom in really good components of selective oxidation and inspire innovation and creativity.
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Extra resources for New Developments in Selective Oxidation by Heterogeneous Catalysis: Proceedings
4. Decomposition of hydrogen peroxide Experiments for Hz02decomposition were carried out in the same reactor as for H202 synthesis in the presence of 0, only. Results, shown in Table 5, indicate that Pd deposited on the hydrophilic supports was very efficient for catalytic hydrogen peroxide decomposition. 5 in Tables 2 and 5). 0) leads to some rise 39 in the rate of H,O, decomposition, but it also results in a strong increase in activity for H,O, synthesis. These results stress the importance of the appropriate proportion between hydrophobic and hydrophilic components.
Have mentioned the preparation of mono-oxidized B-CD  by oxidation over a Pt catalyst, without giving any characterization of the products. In our hands the oxidation of B-CD over different catalyst systems did not result in selective formation of the mono- or dicarboxylic acid . A number of side products are formed, which could be partly identified. At the start of the reaction, two products were present in relatively large amounts. By comparison with the reaction mixture of the oxidation of maltoheptaose these compounds appeared to be linear maltohexaose (MD6) and C1-oxidized maltohexaose (MD6ox).
Van Bekkum, Appl. Cuful. 33 (1987) 361. 45. E. van Dam, P. G. Kieboom and H. van Bekkum, Appl. 33 (1987) 373. 46. E. G. Kieboom and H. van Bekkum, Recl. Truv. Chim. Pays-Bus 108 (1989) 404. 47. J. M. B. Marin, Curbohydr. Res. 204 (1990) 121. 48. J. M. B. Marin, Curbohydr. , in press. 49. I. Leupold, M. Wiesner and W. Fritsche-Lang, Proc. Eurocarb V, Prague, 1989, p. D-1; W. I. Leupold and M. G. 50. C. Nand, Cient. Cult. (Sao Paulo) 36 (1984) 442. 51. E. Scholander, Carbohydr. Res. 73 (1979) 302.
New Developments in Selective Oxidation by Heterogeneous Catalysis: Proceedings by P. Ruiz, B. Delmon